Foid-bearing syenite cognate xenoliths represent fragments of the upper peripheral parts of the K-phonolitic portions of the 79 AD magma chamber, wrenched during the explosive eruption. Abundant multiphase fluid inclusions are hosted within K-feldspar and coexist with rare silicate melt inclusions. This gives evidence to the exsolution of a magmatic volatile-rich phase from the peripheral parts of the silicate magma chamber. The characterization of daughter mineral assemblage of these fluid inclusions, by SEM-EDS and Raman spectroscopy, indicates two ubiquitous main components: Na-K chlorides (halite + sylvite) and Na-Ca carbonates (calcite ± nahcolite). Microthermometric experiments indicate nearly magmatic trapping temperatures (760°C to 830°C) of the homogeneous chloride-carbonate liquid. Cooling of such liquid produces two immiscible melt phases (chlorides and carbonates) at 455-435°C. This suggests that a hypersaline-carbonate fluid, exsolved from the silicate magma, can further experience another unmixing event that would occur in essentially «post-magmatic» environment.

Item Type:	Refereed Article
Research Division:	Earth Sciences
Research Group:	Geology
Research Field:	Igneous and Metamorphic Petrology
Objective Division:	Expanding Knowledge
Objective Group:	Expanding Knowledge
Objective Field:	Expanding Knowledge in the Earth Sciences
Author:	Kamenetsky, VS (Professor Vadim Kamenetsky)
ID Code:	39060
Year Published:	2005
Web of Science® Times Cited:	7
Deposited By:	Centre for Ore Deposit Research - CODES CoE
Deposited On:	2005-08-01
Last Modified:	2010-08-25
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