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Oxidation reactions using water, hydrogen peroxide and halogens to give pallada(IV)cyclopentane complexes PdX(C4H8){(pz)3BH} (X = OH, Cl, Br, I). The X-ray strucutre of the hydroxoplatinum(IV) complex Pt(OH)Me2{(pz)3BH}, formed using water as an oxidant

Citation

Canty, AJ and Fritsche, SD and Jin, H and Skelton, BW and White, AH, Oxidation reactions using water, hydrogen peroxide and halogens to give pallada(IV)cyclopentane complexes PdX(C4H8){(pz)3BH} (X = OH, Cl, Br, I). The X-ray strucutre of the hydroxoplatinum(IV) complex Pt(OH)Me2{(pz)3BH}, formed using water as an oxidant, Journal of Organometallic Chemistry, 490, (1-2) pp. C18-19. ISSN 0022-328X (1995) [Refereed Article]

DOI: doi:10.1016/0022-328X(94)05310-8

Abstract

The pallada(II)cyclopentane reagent [Pd(C 4H 8{(pz) 3BH}] -, generated by addition of potassium tris(pyrazol-1-yl)borate to the tetramethylethylenediamine analogue, reacts with water or hydrogen peroxide to give hydroxopalladium(IV) complex Pd(OH)(C 4H 8){(pz) 3BH}. Similar oxidation reactions occur with phenyliodonium dichloride, bromine and iodine to give PdX(C 4H 8){(pz) 3BH} (X = Cl, Br, I). The hydroxoplatinum(IV) complex Pt(OH)Me 2{(pz) 3BH} has been obtaine reaction of [PtMe 2(SEt 2)] 2 with K[(pz) 3BH], followed by addition of water, and its structure determined by an X-ray diffraction study. © 1995.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Canty, AJ (Professor Allan Canty)
Author:Fritsche, SD (Mr Steven Dirk Fritsche)
Author:Jin, H (Dr Hong Jin)
ID Code:3732
Year Published:1995
Web of Science® Times Cited:31
Deposited By:Chemistry
Deposited On:1995-08-01
Last Modified:2011-08-22
Downloads:0

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