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Molecular interconversion behaviour in comprehensive two-dimensional gas chromatography


Marriott, PJ and Aryusuk, K and Shellie, RA and Ryan, D and Krisnangkura, K and Schurig, V and Trapp, O, Molecular interconversion behaviour in comprehensive two-dimensional gas chromatography, Journal of Chromatography A, 1033, (1) pp. 135-143. ISSN 0021-9673 (2004) [Refereed Article]

DOI: doi:10.1016/j.chroma.2004.01.035


Comprehensive two-dimensional gas chromatography (GC x GC) is shown to provide information on dynamic molecular behaviour (interconversion), with the interconversion process occurring on both columns in the coupled-column experiment. The experiment requires suitable adjustment of both experimental conditions and relative dimensions of each of the columns. In this case, a longer column than normally employed in GC x GC allows sufficient retention duration on the second column, which permits the typical plateau-shape recognised for the interconversion process to be observed. The extent of interconversion depends on prevailing temperature, retention time, and the phase type. Polyethylene glycol-based phases were found to result in high interconversion kinetics, although terephthalic acid-terminated polyethylene glycol had a lesser extent of interconversion. Much less interconversion was seen for phenyl-methylpolysiloxane and cyclodextrin phases. This suggests that for the oximes, interconversion largely occurs in the stationary phase. Examples of different extents of interconversion in both dimensions are shown, including peak coalescence on the first column with little interconversion on the second column. © 2004 Elsevier B.V. All rights reserved.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Analytical chemistry
Research Field:Separation science
Objective Division:Manufacturing
Objective Group:Instrumentation
Objective Field:Scientific instruments
UTAS Author:Shellie, RA (Associate Professor Robert Shellie)
ID Code:36265
Year Published:2004
Web of Science® Times Cited:19
Deposited By:Chemistry
Deposited On:2007-11-02
Last Modified:2007-11-02

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