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Reversible Sm(III)/Sm(II) Redox Chemistry of an Organosamarium(III) Complex


Wang, J and Amos, RIJ and Frey, A and Gardiner, MG and Cole, ML and Junk, PC, Reversible Sm(III)/Sm(II) Redox Chemistry of an Organosamarium(III) Complex, Organometallics, 24, (10) pp. 2259-2261. ISSN 0276-7333 (2005) [Refereed Article]

Copyright Statement

Copyright 2005 American Chemical Society

DOI: doi:10.1021/om050172a


A binuclear samarium(III) complex featuring the μ- η1η1-bound dianion of 1,4-di-tert-butyl-1,4- diazabuta-1,3-diene has been prepared which exhibits reversible redox behavior, reverting to the samarium(II) precursor when dissolved in tetrahydrofuran. The new samarium(III) complex has been characterized by 1H and 13C NMR spectral data, microanalytical data, magnetic moment measurements in solution, and an X-ray crystal structure determination. © 2005 American Chemical Society.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:F-block chemistry
Objective Division:Manufacturing
Objective Group:Industrial chemicals and related products
Objective Field:Organic industrial chemicals (excl. resins, rubber and plastics)
UTAS Author:Wang, J (Dr Jun Wang)
UTAS Author:Amos, RIJ (Dr Ruth Amos)
UTAS Author:Frey, A (Mr Alistair Frey)
UTAS Author:Gardiner, MG (Associate Professor Michael Gardiner)
ID Code:32964
Year Published:2005
Web of Science® Times Cited:23
Deposited By:Chemistry
Deposited On:2005-08-01
Last Modified:2015-11-04

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