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Reversible Sm(III)/Sm(II) Redox Chemistry of an Organosamarium(III) Complex

journal contribution
posted on 2023-05-16, 16:15 authored by Wang, J, Amos, RIJ, Frey, A, Michael GardinerMichael Gardiner, Cole, ML, Junk, PC
A binuclear samarium(III) complex featuring the μ- η1η1-bound dianion of 1,4-di-tert-butyl-1,4- diazabuta-1,3-diene has been prepared which exhibits reversible redox behavior, reverting to the samarium(II) precursor when dissolved in tetrahydrofuran. The new samarium(III) complex has been characterized by 1H and 13C NMR spectral data, microanalytical data, magnetic moment measurements in solution, and an X-ray crystal structure determination. © 2005 American Chemical Society.

History

Publication title

Organometallics

Volume

24

Issue

10

Pagination

2259-2261

ISSN

0276-7333

Department/School

School of Natural Sciences

Publisher

American Chemical Society

Place of publication

Washington

Rights statement

Copyright 2005 American Chemical Society

Repository Status

  • Restricted

Socio-economic Objectives

Organic industrial chemicals (excl. resins, rubber and plastics)

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