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Alkali-Metal, Halide, and Lewis Base Free Monomeric Alkylsamarium(III) Porphyrinogen Complexes of High Stability

Citation

Wang, J and Gardiner, MG and Skelton, BW and White, AH, Alkali-Metal, Halide, and Lewis Base Free Monomeric Alkylsamarium(III) Porphyrinogen Complexes of High Stability, Organometallics, 24, (5) pp. 815-818. ISSN 0276-7333 (2005) [Refereed Article]

DOI: doi:10.1021/om0490233

Abstract

Alkylsamarium(III) complexes of a dimetalated modified porphyrinogen have been synthesized that have strong structural resemblance to samarocene(III) alkyl complexes. The monomeric complexes are free of alkali metals, halides, and coordinating solvent. The methyl and (trimethylsilyl)methyl complexes have been characterized by NMR spectroscopy, X-ray crystal structure determinations, and elemental analyses. Initial reactivity studies highlight the low reactivity of the complexes. © 2005 American Chemical Society.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:f-Block Chemistry
Objective Division:Manufacturing
Objective Group:Industrial Chemicals and Related Products
Objective Field:Organic Industrial Chemicals (excl. Resins, Rubber and Plastics)
Author:Wang, J (Dr Jun Wang)
Author:Gardiner, MG (Associate Professor Michael Gardiner)
ID Code:32961
Year Published:2005
Web of Science® Times Cited:23
Deposited By:Chemistry
Deposited On:2005-08-01
Last Modified:2006-03-31
Downloads:0

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