eCite Digital Repository

Kimberlite melts rich in alkali chlorides and carbonates: A potent metasomatic agent in the mantle


Kamenetsky, M and Sobolev, AV and Kamenetsky, VS and Maas, R and Danyushevsky, LV and Thomas, R and Pokhilenko, NP and Sovolev, NV, Kimberlite melts rich in alkali chlorides and carbonates: A potent metasomatic agent in the mantle, Geology, 32, (10) pp. 845-848. ISSN 0091-7613 (2004) [Refereed Article]

DOI: doi:10.1130/G20821.1


Kimberlite magmas, as the deepest probe into Earth's mantle (>150 km), can supply unique information about volatile components (hydrogen, carbon, chlorine, sulfur) in mantle-derived melts and fluids. All known kimberlite rocks are not suitable for studies of mantle volatiles because of their pervasive postmagmatic alteration; however, this study discusses an exceptionally fresh group I kimberlites (<0.5 wt% H 2O) from the Udachnaya-East diamondiferous pipe in Siberia. Kimberlite groundmass, in addition to euhedral olivine and calcite, is extremely enriched (at least 8 wt%) in water-soluble alkali chlorides, alkali carbonates, and sulfates (ratio 5:3:1), and often shows immiscibility textures. A primary magmatic origin of alkali chlorides and alkali carbonates is confirmed by the study of strontium isotopes in the water- and dilute acid-leachates of the groundmass ( 87Sr/86Sr = 0.7069 and 0.7050) that contrast with much more radiogenic isotope composition of the Cambrian platform sedimentary rocks and the Udachnaya-East mine-site brines. Melt inclusions in groundmass olivine, composed of halite, sylvite, alkali-Ca carbonates, phlogopite, olivine, and CO2 fluid, were used to determine the composition and evolution of the kimberlite melt prior to emplacement. Melt inclusions show immiscibility between chloride and carbonate liquids at <600 °C in heating stage experiments. The chloride and carbonate enrichment in the kimberlite parental magma suggests the presence of a powerful agent for chemical modifications (metasomatism) in the mantle and crust. © 2004 Geological Society of America.

Item Details

Item Type:Refereed Article
Research Division:Earth Sciences
Research Group:Geology
Research Field:Igneous and metamorphic petrology
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the earth sciences
UTAS Author:Kamenetsky, M (Dr Maya Kamenetsky)
UTAS Author:Kamenetsky, VS (Professor Vadim Kamenetsky)
UTAS Author:Danyushevsky, LV (Professor Leonid Danyushevsky)
ID Code:32653
Year Published:2004
Web of Science® Times Cited:215
Deposited By:Centre for Ore Deposit Research - CODES CoE
Deposited On:2004-08-01
Last Modified:2008-09-26

Repository Staff Only: item control page