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Increased Stability of NO and NS Heterocyclic Carbenes?
Citation
Graham, DC and Yates, BF, Increased Stability of NO and NS Heterocyclic Carbenes?, Australian Journal of Chemistry, 57, (4) pp. 359-364. ISSN 0004-9425 (2004) [Refereed Article]
DOI: doi:10.1071/CH03248
Abstract
Density functional theory has been used to investigate the effects of alkylation and oxidation on the stability of NO and NS heterocyclic carbenes. While O- and S-alkylation leads to a dramatic increase in stability with respect to dimerization, oxidation of the NS heterocyclic carbene to form the sulphoxide appears to have the opposite effect.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Organic chemistry |
| Research Field: | Physical organic chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Graham, DC (Dr David Graham) |
| UTAS Author: | Yates, BF (Professor Brian Yates) |
| ID Code: | 31987 |
| Year Published: | 2004 |
| Web of Science® Times Cited: | 3 |
| Deposited By: | Chemistry |
| Deposited On: | 2004-08-01 |
| Last Modified: | 2005-05-30 |
| Downloads: | 0 |
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