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Increased Stability of NO and NS Heterocyclic Carbenes?

Citation

Graham, DC and Yates, BF, Increased Stability of NO and NS Heterocyclic Carbenes?, Australian Journal of Chemistry, 57, (4) pp. 359-364. ISSN 0004-9425 (2004) [Refereed Article]

DOI: doi:10.1071/CH03248

Abstract

Density functional theory has been used to investigate the effects of alkylation and oxidation on the stability of NO and NS heterocyclic carbenes. While O- and S-alkylation leads to a dramatic increase in stability with respect to dimerization, oxidation of the NS heterocyclic carbene to form the sulphoxide appears to have the opposite effect.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic Chemistry
Research Field:Physical Organic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Graham, DC (Dr David Graham)
Author:Yates, BF (Professor Brian Yates)
ID Code:31987
Year Published:2004
Web of Science® Times Cited:2
Deposited By:Chemistry
Deposited On:2004-08-01
Last Modified:2005-05-30
Downloads:0

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