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Increased Stability of NO and NS Heterocyclic Carbenes?
Density functional theory has been used to investigate the effects of alkylation and oxidation on the stability of NO and NS heterocyclic carbenes. While O- and S-alkylation leads to a dramatic increase in stability with respect to dimerization, oxidation of the NS heterocyclic carbene to form the sulphoxide appears to have the opposite effect.
History
Publication title
Australian Journal of ChemistryVolume
57Issue
4Pagination
359-364ISSN
0004-9425Department/School
School of Natural SciencesPublisher
CSIRO PublishingPlace of publication
CollingwoodRepository Status
- Restricted