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Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-kappa N-2(3)]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-kappa N-2(3)]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)methanone-kappa N-2(3)]chloroiron(II)} methanol disolvate (ca 300 K)

Citation

Batten, MP and Canty, AJ and Cavell, KJ and Ruether, T and Skelton, BW and White, AH, Tris[bis(1-methyl-1H-imidazol-2-yl)methanone-kappa N-2(3)]iron(II) dichloride 5.5-hydrate, cis-bis[bis(1-methyl-1H-imidazol-2-yl)methanone-kappa N-2(3)]dichloroiron(II) (ca 153 K) and di-mu-chloro-bis{[bis(1-methyl-1H-imidazol-2-yl)methanone-kappa N-2(3)]chloroiron(II)} methanol disolvate (ca 300 K), Acta Crystallographica Section C - Crystal Structure Communications, 60, (7) pp. m316-m319. ISSN 0108-2701 (2004) [Refereed Article]

DOI: doi:10.1107/S0108270104010881

Abstract

The first of the title compounds, [Fe(C 9H 10N 4O) 3]Cl 2·5.5H 2O, is the first structurally characterized homoleptic tris[bis(imidazol-2-yl) ketonej-metal complex to be structurally defined. In the second of the title compounds, [FeCl 2(C 9H 10N 4O) 2], a pair of monodentate donors supplants one of the bidentate ligands. In the third complex, [Fe 2Cl 4(C 9H 10N 4O) 2]·2CH 3OH, a centrosymmetric binuclear compound with a pair of bridging chloride ligands, the introduction of a third chloro ligand results in five-coordination about each of the metal atoms; the environments of the latter are square pyramidal, with a chloro ligand at the apex and the two bidentate arrays about the base of the pyramid.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Batten, MP (Mr Michael Batten)
Author:Canty, AJ (Professor Allan Canty)
Author:Cavell, KJ (Professor Kingsley Cavell)
Author:Ruether, T (Dr Thomas Ruether)
ID Code:31956
Year Published:2004
Web of Science® Times Cited:6
Deposited By:Chemistry
Deposited On:2004-08-01
Last Modified:2011-09-19
Downloads:0

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