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Bis[tris(1-methyl-1H-imidazol-2-yl)phosphine-kappa N-3(3)]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-kappa N-3(3)]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K)
Citation
Batten, MP and Canty, AJ and Cavell, KJ and Ruether, T and Skelton, BW and White, AH, Bis[tris(1-methyl-1H-imidazol-2-yl)phosphine-kappa N-3(3)]iron(II) tetrachloroferrate(II) methanol tetrasolvate (ca 153 K) and bis[tris(1-methyl-1H-imidazol-2-yl)methanol-kappa N-3(3)]iron(III) bis[tetrachloroferrate(III)] chloride (redetermination, ca 153 K), Acta Crystallographica Section C - Crystal Structure Communications, 60, (7) pp. m311-m313. ISSN 0108-2701 (2004) [Refereed Article]
DOI: doi:10.1107/S0108270104010868
Abstract
The first of the title compounds, [Fe(C 12H 15N 6P) 2][FeCl 4]-4CH 4O, is the first homoleptic bis(ligand)iron(II) species reported for this phosphorus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1-methyl-1H- imidazol-2-yl)methanol counterpart, the second of the title compounds, [Fe(C 13H 16N 6O) 2][FeCl 4] 2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Batten, MP (Mr Michael Batten) |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| UTAS Author: | Cavell, KJ (Professor Kingsley Cavell) |
| UTAS Author: | Ruether, T (Dr Thomas Ruether) |
| ID Code: | 31955 |
| Year Published: | 2004 |
| Web of Science® Times Cited: | 9 |
| Deposited By: | Chemistry |
| Deposited On: | 2004-08-01 |
| Last Modified: | 2011-09-19 |
| Downloads: | 0 |
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