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Bis[tris(pyridin-2-yl)methanol-kappa 2N,N ']palladium(II) dinitrate at 150 and 298 K
Citation
Canty, AJ and Skelton, BW and Traill, PR and White, AH, Bis[tris(pyridin-2-yl)methanol-kappa 2N,N ']palladium(II) dinitrate at 150 and 298 K, Acta Crystallographica Section C - Crystal Structure Communications, 60, (7) pp. m305-m307. ISSN 0108-2701 (2004) [Refereed Article]
DOI: doi:10.1107/S0108270104010893
Abstract
The title complex, [Pd{(py)3COH}2](NO 3)2, where (py)3COH is tris(pyridin-2-yl) methanol (C16H13N3O), studied at 150 and 298 K, has the potentially tridentate ligands present as bidentate ligands, with the Pd atom at a centre of symmetry. At 150 K, the Pd - N distances are 2.022 (3) and 2.026 (3) Å. The mean planes of the coordinated pyridine groups form dihedral angles of 42.1 (1) and 45.3 (1)° (at 150 K) with the coordination plane; the uncoordinated rings situated either side of the coordination plane form dihedral angles of 42.2 (1)° with it. The nitrate ions are regular and interact weakly with the hydroxyl group.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Canty, AJ (Professor Allan Canty) |
| Author: | Traill, PR (Mr Peter Traill) |
| ID Code: | 31953 |
| Year Published: | 2004 |
| Web of Science® Times Cited: | 2 |
| Deposited By: | Chemistry |
| Deposited On: | 2004-08-01 |
| Last Modified: | 2011-09-19 |
| Downloads: | 0 |
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