eCite Digital Repository

Chloro(phenyl)(1H-pyrazole-kappa N-2)-(triphenylphosphine-kappa P)palladium(II)


Canty, AJ and Skelton, BW and White, AH, Chloro(phenyl)(1H-pyrazole-kappa N-2)-(triphenylphosphine-kappa P)palladium(II), Acta Crystallographica Section C - Crystal Structure Communications, 60, (8) pp. m405-m406. ISSN 0108-2701 (2004) [Refereed Article]

DOI: doi:10.1107/S010827010401491X


In the title compound, [Pd(C6H5)Cl(C 3H4N2)(P(C6H5) 3}], the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four monodentate Cl, P, N and (non-carbenoid) C ligands in a square-planar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra- and intermolecular component.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Organometallic chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Canty, AJ (Professor Allan Canty)
ID Code:31952
Year Published:2004
Web of Science® Times Cited:1
Deposited By:Chemistry
Deposited On:2004-08-01
Last Modified:2011-09-19

Repository Staff Only: item control page