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Chloro(phenyl)(1H-pyrazole-kappa N-2)-(triphenylphosphine-kappa P)palladium(II)

Citation

Canty, AJ and Skelton, BW and White, AH, Chloro(phenyl)(1H-pyrazole-kappa N-2)-(triphenylphosphine-kappa P)palladium(II), Acta Crystallographica Section C - Crystal Structure Communications, 60, (8) pp. m405-m406. ISSN 0108-2701 (2004) [Refereed Article]

DOI: doi:10.1107/S010827010401491X

Abstract

In the title compound, [Pd(C6H5)Cl(C 3H4N2)(P(C6H5) 3}], the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four monodentate Cl, P, N and (non-carbenoid) C ligands in a square-planar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra- and intermolecular component.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Canty, AJ (Professor Allan Canty)
ID Code:31952
Year Published:2004
Web of Science® Times Cited:1
Deposited By:Chemistry
Deposited On:2004-08-01
Last Modified:2011-09-19
Downloads:0

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