329 Miura - Anal Sci 20 (2004) 363 - 367.pdf (43.45 kB)
Spectrophotometric Determination of Sulfide in the Presence of Sulfite and Thiosulfate via the Precipitation of Bismuth(III) Sulfide
journal contribution
posted on 2023-05-16, 15:33 authored by Miura, Y, Fujisaki, M, Paul HaddadPaul HaddadA photometric method has been developed for the determination of sulfide at 10-5 mol dm-3 levels, which is based on the reaction of sulfide with a given excess amount of bismuth(III) to form a precipitate of bismuth(III) sulfide and on the spectrophotometric measurement of the residual bismuth(III) at 335 nm after extracting with bismuthiol II reagent from an aqueous solution containing acetate buffer into benzene. The presence of sulfite and thiosulfate up to 0.002 mol dm-3 did not cause any interference in the determination of sulfide, because both sulfite and thiosulfate do not produce any precipitate with bismuth(III). A linear calibration plot with a negative slope was obtained for sulfide over the range of 5.00 x 10-7 - 3.00 x 10-5 mol dm-3 (16.0 - 960 ppb). An experimental calibration plot was in accord with the theoretical plot, taking into account the known excess of bismuth(III), showing that the reaction of sulfide with bismuth(III) proceeded to completion. The relative standard deviation of results from 10 replicate determinations of standard sulfide (2.00 x 10-5 mol dm-3) was 0.44%. The proposed method was successfully applied to the determination of sulfide in hot-spring water samples without any pretreatment.
History
Publication title
Analytical SciencesVolume
20Pagination
363-367ISSN
0910-6340Department/School
School of Natural SciencesPublisher
The Japan Society for Analytical ChemistryPlace of publication
TokyoRights statement
Copyright © 2004 The Japan Society for Analytical ChemistryRepository Status
- Open