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Lanthanide(II) and -(III) Porphyrinogens - Rational Synthesis and Derivatisation of Mononuclear, Alkali-Metal-Free Lanthanide(II) and -(III) meso-Octaalkylporphyrinogen Complexes

journal contribution
posted on 2023-05-16, 15:31 authored by Wang, J, Dick, AKJ, Michael GardinerMichael Gardiner, Brian YatesBrian Yates, Peacock, EJ, Skelton, BW, White, AH
Modifying the porphyrinogen framework in lanthanide porphyrinogen complexes by trans-N,N′-dimethylation results in Sm II and Sm III derivatives that are remarkably simple in structure and formulation, and are amenable to highly controllable further reaction chemistry. The Sm II bis(tetrahydrofuran) adduct, Sm III chloride and bis(trimethylsilyl)amide complexes have been synthesised and characterised by elemental analysis, 1H and 13C NMR spectroscopy and X-ray crystal structure determinations. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

History

Publication title

European Journal of Inorganic Chemistry

Issue

10

Pagination

1992-1995

ISSN

1434-1948

Department/School

School of Natural Sciences

Publisher

Wiley-VCH

Place of publication

Weinheim

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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