eCite Digital Repository

Lanthanide(II) and -(III) Porphyrinogens - Rational Synthesis and Derivatisation of Mononuclear, Alkali-Metal-Free Lanthanide(II) and -(III) meso-Octaalkylporphyrinogen Complexes

Citation

Wang, J and Dick, AKJ and Gardiner, MG and Yates, BF and Peacock, EJ and Skelton, BW and White, AH, Lanthanide(II) and -(III) Porphyrinogens - Rational Synthesis and Derivatisation of Mononuclear, Alkali-Metal-Free Lanthanide(II) and -(III) meso-Octaalkylporphyrinogen Complexes, European Journal of Inorganic Chemistry, (10) pp. 1992-1995. ISSN 1434-1948 (2004) [Refereed Article]

DOI: doi:10.1002/ejic.200300965

Abstract

Modifying the porphyrinogen framework in lanthanide porphyrinogen complexes by trans-N,N′-dimethylation results in Sm II and Sm III derivatives that are remarkably simple in structure and formulation, and are amenable to highly controllable further reaction chemistry. The Sm II bis(tetrahydrofuran) adduct, Sm III chloride and bis(trimethylsilyl)amide complexes have been synthesised and characterised by elemental analysis, 1H and 13C NMR spectroscopy and X-ray crystal structure determinations. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Wang, J (Dr Jun Wang)
Author:Dick, AKJ (Mr Andrew Dick)
Author:Gardiner, MG (Associate Professor Michael Gardiner)
Author:Yates, BF (Professor Brian Yates)
Author:Peacock, EJ (Dr Evan Peacock)
ID Code:31689
Year Published:2004
Web of Science® Times Cited:18
Deposited By:Chemistry
Deposited On:2004-08-01
Last Modified:2011-10-04
Downloads:0

Repository Staff Only: item control page