File(s) not publicly available
Lanthanide(II) and -(III) Porphyrinogens - Rational Synthesis and Derivatisation of Mononuclear, Alkali-Metal-Free Lanthanide(II) and -(III) meso-Octaalkylporphyrinogen Complexes
journal contribution
posted on 2023-05-16, 15:31 authored by Wang, J, Dick, AKJ, Michael GardinerMichael Gardiner, Brian YatesBrian Yates, Peacock, EJ, Skelton, BW, White, AHModifying the porphyrinogen framework in lanthanide porphyrinogen complexes by trans-N,N′-dimethylation results in Sm II and Sm III derivatives that are remarkably simple in structure and formulation, and are amenable to highly controllable further reaction chemistry. The Sm II bis(tetrahydrofuran) adduct, Sm III chloride and bis(trimethylsilyl)amide complexes have been synthesised and characterised by elemental analysis, 1H and 13C NMR spectroscopy and X-ray crystal structure determinations. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.
History
Publication title
European Journal of Inorganic ChemistryIssue
10Pagination
1992-1995ISSN
1434-1948Department/School
School of Natural SciencesPublisher
Wiley-VCHPlace of publication
WeinheimRepository Status
- Restricted