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Determination of Inorganic Selenium Species in Marine Waters by Hydride Generation-AFS

Citation

Wake, BD and Butler, ECV and Featherstone, AM and Virtue, P and Averty, B and Michel, P, Determination of Inorganic Selenium Species in Marine Waters by Hydride Generation-AFS, Australian Journal of Chemistry, 57, (10) pp. 937-943. ISSN 0004-9425 (2004) [Refereed Article]

DOI: doi:10.1071/CH04072

Abstract

A method based on hydride generation with cryogenic trapping and atomic fluorescence detection was developed that is capable of determining both inorganic Se species (SeIV and SeVI) while at sea. Evaluation of the system for optimal performance was made for each stage of the analysis and detection sequence, as well as for the SeVI reduction step. A detection limit of 0.4 ng L-1 Se in a 10mL sample was achieved using this method. Precision was better than 3.5% for 25, 100, and 1000 ng L-1 SeIV standard solutions. Accuracy was determined by recovery studies using natural samples and a certified reference seawater (NASS-5).

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic Chemistry
Research Field:Organic Chemistry not elsewhere classified
Objective Division:Environment
Objective Group:Physical and Chemical Conditions of Water
Objective Field:Physical and Chemical Conditions of Water in Marine Environments
Author:Wake, BD (Miss Bronwyn Wake)
Author:Butler, ECV (Dr Edward Butler)
Author:Featherstone, AM (Dr Alison Featherstone)
Author:Virtue, P (Associate Professor Patti Virtue)
ID Code:31680
Year Published:2004
Web of Science® Times Cited:3
Deposited By:IASOS
Deposited On:2004-08-01
Last Modified:2010-04-13
Downloads:0

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