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Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)(2)(mu-SEt2)](2) and PtCl(p-Tol)(bpy) (bpy=2,2 '-bipyridine)

Citation

Casado, MA and Canty, AJ and Lutz, M and Patel, J and Spek, AL and Sun, H and van Koten, G, Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)(2)(mu-SEt2)](2) and PtCl(p-Tol)(bpy) (bpy=2,2 '-bipyridine), Inorganica Chimica Acta, 327 pp. 15-19. ISSN 0020-1693 (2002) [Refereed Article]

DOI: doi:10.1016/S0020-1693(01)00681-8

Abstract

The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2′-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(μ-SEt2)]2. © 2002 Published by Elsevier Science B.V.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Canty, AJ (Professor Allan Canty)
Author:Patel, J (Mr Jim Patel)
Author:Sun, H (Dr Haishun Sun)
ID Code:24312
Year Published:2002
Web of Science® Times Cited:11
Deposited By:Chemistry
Deposited On:2002-08-01
Last Modified:2011-08-02
Downloads:0

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