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Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)(2)(mu-SEt2)](2) and PtCl(p-Tol)(bpy) (bpy=2,2 '-bipyridine)
Citation
Casado, MA and Canty, AJ and Lutz, M and Patel, J and Spek, AL and Sun, H and van Koten, G, Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)(2)(mu-SEt2)](2) and PtCl(p-Tol)(bpy) (bpy=2,2 '-bipyridine), Inorganica Chimica Acta, 327 pp. 15-19. ISSN 0020-1693 (2002) [Refereed Article]
DOI: doi:10.1016/S0020-1693(01)00681-8
Abstract
The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2′-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(μ-SEt2)]2. © 2002 Published by Elsevier Science B.V.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Organometallic chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| UTAS Author: | Patel, J (Mr Jim Patel) |
| UTAS Author: | Sun, H (Dr Haishun Sun) |
| ID Code: | 24312 |
| Year Published: | 2002 |
| Web of Science® Times Cited: | 13 |
| Deposited By: | Chemistry |
| Deposited On: | 2002-08-01 |
| Last Modified: | 2011-08-02 |
| Downloads: | 0 |
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