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Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

Citation

Nielsen, DJ and Magill, AM and Yates, BF and Cavell, KJ and Skelton, BW and White, AH, Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex, Chemical Communications, (21) pp. 2500-2501. ISSN 1359-7345 (2002) [Refereed Article]

DOI: doi:10.1039/b207020k

Abstract

Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Physical Chemistry (incl. Structural)
Research Field:Catalysis and Mechanisms of Reactions
Objective Division:Manufacturing
Objective Group:Industrial Chemicals and Related Products
Objective Field:Organic Industrial Chemicals (excl. Resins, Rubber and Plastics)
Author:Nielsen, DJ (Mr David Nielsen)
Author:Magill, AM (Miss Alison Magill)
Author:Yates, BF (Professor Brian Yates)
ID Code:24311
Year Published:2002
Web of Science® Times Cited:57
Deposited By:Chemistry
Deposited On:2002-08-01
Last Modified:2011-09-29
Downloads:0

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