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Experimental and computational study of a reductive elimination mechanism in a methyl-Pd(II)-CNC carbene complex

journal contribution
posted on 2023-05-16, 13:31 authored by Nielsen, DJ, Magill, AM, Brian YatesBrian Yates, Cavell, KJ, Skelton, BW, White, AH
Experimental and density functional studies on the decomposition of a novel palladium-methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

History

Publication title

Chemical Communications

Issue

21

Pagination

2500-2501

ISSN

1359-7345

Department/School

School of Natural Sciences

Publisher

The Royal Society of Chemistry

Place of publication

Cambridge, England, UK

Repository Status

  • Restricted

Socio-economic Objectives

Organic industrial chemicals (excl. resins, rubber and plastics)

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