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C-27 Apocarotenoids in the flowers of Boronia megastigma (Nees)

Citation

Cooper, C and Davies, NW and Menary, RC, C-27 Apocarotenoids in the flowers of Boronia megastigma (Nees), Journal of Agricultural and Food Chemistry, 51, (8) pp. 2384-2389. ISSN 0021-8561 (2003) [Refereed Article]

DOI: doi:10.1021/jf026007c

Abstract

Five C-27 apocarotenoids were detected in acetone extracts of the flowers of Boronia megastigma (Nees) using HPLC with UV-vis photodiode array and MS detection. Comparison of methylated and unmethylated extracts aided identification when considered with the UV-vis and MS data. The five apocarotenoids identified here were hydroxy-apo-10′-carotenoic acid (1), methyl hydroxy-apo-10′-carotenoate (2), apo-10′-carotenoic acid (3), apo-10′-carotenal (4), and methyl apo-10′-carotenoate (5). The data obtained was not sufficient to allow the specific isomeric forms to be unequivocally identified. The results further support speculation that the C-13 norisoprenoids found in boronia are derived from C-40 carotenoids. Possible parent molecules of β-ionone, an important component of boronia extract, were identified. An understanding of C-13 norisoprenoid biosynthesis may assist in the selection and postharvest processing of boronia flowers for flavor and fragrance applications.

Item Details

Item Type:Refereed Article
Research Division:Agricultural and Veterinary Sciences
Research Group:Horticultural Production
Research Field:Horticultural Production not elsewhere classified
Objective Division:Plant Production and Plant Primary Products
Objective Group:Horticultural Crops
Objective Field:Horticultural Crops not elsewhere classified
Author:Cooper, C (Dr Christopher Cooper)
Author:Davies, NW (Associate Professor Noel Davies)
Author:Menary, RC (Professor Robert Menary)
ID Code:23733
Year Published:2003
Web of Science® Times Cited:16
Deposited By:Agricultural Science
Deposited On:2003-08-01
Last Modified:2005-07-27
Downloads:0

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