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Agostic deformations based on electron delocalization in the alkyllithium-complex [{2-(Me3Si)2CLiC5H4N}2
Citation
Scherer, W and Sirsch, P and Grosche, M and Spiegler, M and Mason, SA and Gardiner, MG, Agostic deformations based on electron delocalization in the alkyllithium-complex [{2-(Me3Si)2CLiC5H4N}2, Chemical Communications, (20) pp. 2072-2073. ISSN 1359-7345 (2001) [Refereed Article]
DOI: doi:10.1039/b105452j
Abstract
Topological analysis of experimental and theoretical charge densities in the title complex [{2-(Me 3 Si) 2 CLiC 5 H 4 N} 2 ] 1 reveals the nature of the agostic deformation postulated for this complex: delocalization of the Liâ€"C bonding electrons over the entire agostic alkyl group controls the formation of an acute Liâ€"Câ€"Si angle and thus a sufficient electronic saturation of the electron deficient lithium atom via secondary interactions. © 2001 Royal Society of Chemistry.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Other Chemical Sciences |
| Research Field: | Organometallic Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
| ID Code: | 22197 |
| Year Published: | 2001 |
| Web of Science® Times Cited: | 39 |
| Deposited By: | Chemistry |
| Deposited On: | 2001-08-01 |
| Last Modified: | 2011-08-03 |
| Downloads: | 0 |
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