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Approaches to enhancing the sensitivity of capillary electrophoresis methods for the determination of inorganic and small organic anions
Citation
Breadmore, MC and Haddad, PR, Approaches to enhancing the sensitivity of capillary electrophoresis methods for the determination of inorganic and small organic anions, Electrophoresis, 22, (12) pp. 2464-2489. ISSN 0173-0835 (2001) [Refereed Article]
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Copyright Statement
The definitive published version is available online at: http://interscience.wiley.com
Official URL: http://interscience.wiley.com
DOI: doi:10.1002/1522-2683(200107)22:12<2464::AID-ELPS2464>3.0.CO;2-U
Abstract
One of the major problems facing the development of capillary electrophoresis (CE) is the relatively high limits of detection when compared to traditional high-performance liquid chromatographic (HPLC) methods. While the use of an alternative detector can offer better sensitivity, a more universal approach is sample preconcentration. Numerous on-line methods have been developed to improve the sensitivity of CE, and are based on electrophoretic principles, chromatographic principles, or a combination of both. This review will discuss all forms of on-line preconcentration methods for CE, with emphasis given to those that have shown particular merit when applied to inorganic and small organic anions.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | On-line preconcentration • Stacking • Solid-phase extraction • Capillary electrophoresis • Review |
| Research Division: | Chemical Sciences |
| Research Group: | Analytical chemistry |
| Research Field: | Separation science |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Breadmore, MC (Professor Michael Breadmore) |
| UTAS Author: | Haddad, PR (Professor Paul Haddad) |
| ID Code: | 22185 |
| Year Published: | 2001 |
| Web of Science® Times Cited: | 89 |
| Deposited By: | Chemistry |
| Deposited On: | 2001-08-01 |
| Last Modified: | 2010-02-08 |
| Downloads: | 1 View Download Statistics |
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