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A non-suppressed conductivity detection ion chromatographic method using a weakly acidic cation-exchange column (Tosoh TSKgel OApak-A) was developed for the simultaneous separation and determination of common inorganic anions (Cl–, NO3– and SO42-) and cations (Na+, NH4+, K+, Mg2+ and Ca2+). A satisfactory separation of these anions and cations on the weakly acidic cation-exchange column was achieved in 25 min by elution with a mixture of 1.6 mmol L–1 pyridine-2,6-dicarboxylic acid and 8.0 mmol L–1 18-crown-6 at flow rate of 1.0 mL min–1. On this weakly acidic cation-exchange resin, anions were retained by an ion-exclusion mechanism and cations by a cation-exchange mechanism. The linear range of the peak area calibration curves for all analytes were up to two orders of magnitude. The detection limits calculated at S/N = 3 ranged from 0.25 to 1.9 µmol L–1 for anions and cations. The ion-exclusion chromatography–cation-exchange chromatography method developed in this work was successfully applied to the simultaneous determination of major inorganic anions and cations in rainwater, tap water and snow water samples.

Item Type:	Refereed Article
Research Division:	Chemical Sciences
Research Group:	Analytical Chemistry
Research Field:	Separation Science
Objective Division:	Expanding Knowledge
Objective Group:	Expanding Knowledge
Objective Field:	Expanding Knowledge in the Chemical Sciences
Author:	Haddad, PR (Professor Paul Haddad)
ID Code:	22165
Year Published:	2001
Web of Science® Times Cited:	10
Deposited By:	Chemistry
Deposited On:	2001-08-01
Last Modified:	2011-08-03
Downloads:	0