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Carbon-oxygen bond formation at organopalladium centres
Citation
Canty, AJ and Denney, MC and Skelton, BW and White, AH, Carbon-oxygen bond formation at organopalladium centres, Inorganic Chemistry Communications, 4, (11) pp. 648-650. ISSN 1387-7003 (2001) [Refereed Article]
DOI: doi:10.1016/S1387-7003(01)00296-9
Abstract
The reaction of PdMe2(bpy) (bpy = 2,2′-bipyridine) with diaroyl peroxides is a complex process in which initial oxidation of Pd(II) is followed by methyl group exchange between an undetected Pd(IV) intermediate and PdMe2(bpy) to give PdMe(O2CAr)(bpy) and PdMe3(O2CAr)(bpy); the latter Pd(IV) complex decomposes by elimination of Me-Me to give additional PdMe(O2CAr)(bpy) which reacts with (ARCO2)2 to give Me - O2CAr and Pd(O2CAr)2(bpy). The complexes Pd(O2CPh)2(L2) (L2 = bpy, N, N, N′, N′-tetramethylethylyenediamine) have been characterised by X-ray diffraction. © 2001 Elsevier Science B.V. All rights reserved.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Organometallic chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| UTAS Author: | Denney, MC (Mrs Melanie Denney) |
| ID Code: | 22028 |
| Year Published: | 2001 |
| Web of Science® Times Cited: | 13 |
| Deposited By: | Chemistry |
| Deposited On: | 2001-08-01 |
| Last Modified: | 2011-08-03 |
| Downloads: | 0 |
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