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Fe3+ as a reoxidant for Nafion immobilised palladium(II) catalysts
Citation
Seen, AJ and Bellis, JC, Fe3+ as a reoxidant for Nafion immobilised palladium(II) catalysts, Journal of Molecular Catalysis A: Chemical, 164, (1-2) pp. 91-96. ISSN 1381-1169 (2000) [Refereed Article]
DOI: doi:10.1016/S1381-1169(00)00351-4
Abstract
The addition of 1,4-benzoquinone and Fe3+ to [Pd(1,10-phen)2]2+ catalyst systems has been undertaken to assess the ability of these oxidants to increase the ethene dimerisation remover of Nafion immobilised Pd(II) catalysts. Although 1,4-benzoquinone increases the turnover of the Pd(II) catalyst in methanol, it deactivates the catalyst in water. Fe3+ ions have, however, been found to extend the life of the Pd(II) catalyst in water. Fe3+ is effective both in homogeneous solution and when incorporated into Nafion with [Pd(1,10-phen)2]2+. (C) 2000 Elsevier Science B.V.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Physical Chemistry (incl. Structural) |
| Research Field: | Catalysis and Mechanisms of Reactions |
| Objective Division: | Manufacturing |
| Objective Group: | Industrial Chemicals and Related Products |
| Objective Field: | Organic Industrial Chemicals (excl. Resins, Rubber and Plastics) |
| Author: | Seen, AJ (Dr Andrew Seen) |
| Author: | Bellis, JC (Ms Jane Catherine Bellis) |
| ID Code: | 21185 |
| Year Published: | 2000 |
| Web of Science® Times Cited: | 2 |
| Deposited By: | Chemistry |
| Deposited On: | 2001-08-01 |
| Last Modified: | 2011-08-04 |
| Downloads: | 0 |
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