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The structure of a methylpalladium(II) complex of pyridine-2-carboxylato(N-O) and triphenylphosphine (PPh3), [Pd(CH3)(N O)(PPh3)]
Citation
Hambley, TW and Frankcombe, KE and Yates, BF and Cavell, KJ and Knott, RE, The structure of a methylpalladium(II) complex of pyridine-2-carboxylato(N-O) and triphenylphosphine (PPh3), [Pd(CH3)(N O)(PPh3)], Australian Journal of Chemistry, 53, (9) pp. 805-807. ISSN 0004-9425 (2000) [Refereed Article]
DOI: doi:10.1071/CH00064
Abstract
The compound [Pd(CH3)(PPh3)(N-O)] (N-O represents pyridine-2-carboxyIato (pyca)) has been synthesized and the structure determined. The compound crystallized in the monoclinic space group P21/c, a 8.4844(9), b 12.845(2), c 19.690(3) Å, β92.09(1)°, V 2144.4(5) Å3, Z 4, and was refined to an R value of 0.022 on 3551 F. The structure had a distorted square-planar geometry in which the donor nitrogen and phosphine ligands are trans. © CSIRO 2000.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Theoretical and computational chemistry |
| Research Field: | Theoretical quantum chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Frankcombe, KE (Ms Katrina Ellen Frankcombe) |
| UTAS Author: | Yates, BF (Professor Brian Yates) |
| UTAS Author: | Cavell, KJ (Professor Kingsley Cavell) |
| ID Code: | 19765 |
| Year Published: | 2000 |
| Web of Science® Times Cited: | 2 |
| Deposited By: | Chemistry |
| Deposited On: | 2000-08-01 |
| Last Modified: | 2011-08-04 |
| Downloads: | 0 |
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