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The structure of a methylpalladium(II) complex of pyridine-2-carboxylato(N-O) and triphenylphosphine (PPh3), [Pd(CH3)(N O)(PPh3)]

Citation

Hambley, TW and Frankcombe, KE and Yates, BF and Cavell, KJ and Knott, RE, The structure of a methylpalladium(II) complex of pyridine-2-carboxylato(N-O) and triphenylphosphine (PPh3), [Pd(CH3)(N O)(PPh3)], Australian Journal of Chemistry, 53, (9) pp. 805-807. ISSN 0004-9425 (2000) [Refereed Article]

DOI: doi:10.1071/CH00064

Abstract

The compound [Pd(CH3)(PPh3)(N-O)] (N-O represents pyridine-2-carboxyIato (pyca)) has been synthesized and the structure determined. The compound crystallized in the monoclinic space group P21/c, a 8.4844(9), b 12.845(2), c 19.690(3) Å, β92.09(1)°, V 2144.4(5) Å3, Z 4, and was refined to an R value of 0.022 on 3551 F. The structure had a distorted square-planar geometry in which the donor nitrogen and phosphine ligands are trans. © CSIRO 2000.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Theoretical and Computational Chemistry
Research Field:Quantum Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Frankcombe, KE (Ms Katrina Ellen Frankcombe)
Author:Yates, BF (Professor Brian Yates)
Author:Cavell, KJ (Professor Kingsley Cavell)
ID Code:19765
Year Published:2000
Web of Science® Times Cited:2
Deposited By:Chemistry
Deposited On:2000-08-01
Last Modified:2011-08-04
Downloads:0

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