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Platinum-tin bonded complexes, including a structural analysis of the octahedral tris(pyrazol-1-y) borate complex Pt(SnMe3)Me2{(pz)3BH-N,N',N'}

Citation

Canty, AJ and Jin, H and Skelton, BW and White, AH, Platinum-tin bonded complexes, including a structural analysis of the octahedral tris(pyrazol-1-y) borate complex Pt(SnMe3)Me2{(pz)3BH-N,N',N'}, Australian Journal of Chemistry, 52, (5) pp. 417-419. ISSN 0004-9425 (1999) [Refereed Article]

DOI: doi:10.1071/CH98166

Abstract

The platinum(II) complex K [PtMe 2{(pz) 3BH-N,N′}] reacts with SnCl 2Me 2 to form Pt(SnClMe 2)Me 2-{(pz) 3BH-N,N′,N″}([(pz) 3BH]-=tris(pyrazol-1-yl)borate). The closely related complex Pt(SnMe 3)Me 2-{(pz) 3BH-N,N′,N″} has distorted octahedral geometry for platinum with Pt-Sn 2.5727(8) Å. The Pt-N distance trans to the SnMe 3 group [2.237(7) Å] is longer than those trans to the Me groups [2.127(7) and 2.131(6) Å], indicating for the trimethylstannyl group a trans influence which is higher than that for the methyl group.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Canty, AJ (Professor Allan Canty)
Author:Jin, H (Dr Hong Jin)
ID Code:16398
Year Published:1999
Web of Science® Times Cited:10
Deposited By:Chemistry
Deposited On:1999-08-01
Last Modified:2011-08-04
Downloads:0

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