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The Family of M II 3 (TeIVO3)2 (OH)2 (M = Mg, Mn, Co, Ni) Compounds—Prone to Inclusion of Foreign Components into Large Hexagonal Channels

Citation

Eder, F and Weil, M and Missen, OP and Kolitsch, U and Libowitzky, E, The Family of M II 3 (TeIVO3)2 (OH)2 (M = Mg, Mn, Co, Ni) Compounds Prone to Inclusion of Foreign Components into Large Hexagonal Channels, Crystals, 12, (10) Article 380. ISSN 2073-4352 (2022) [Refereed Article]


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DOI: doi:10.3390/cryst12101380

Abstract

MII3(TeIVO3)2(OH)2 (M = Mg, Mn, Co, Ni) compounds crystallize isotypically in the hexagonal space group P63mc (No. 186) with unit-cell parameters of a ≈ 13 Ĺ, c ≈ 5 Ĺ. In the crystal structure, a framework with composition M3(TeO3)2(OH)1.50.5+ defines large hexagonal channels extending along [001] where the remaining OH− anions are located. Crystal-growth studies under mild hydrothermal conditions with subsequent structure analyses on basis of X-ray diffraction methods revealed that parts of other anions present in solution such as CO32−, SO42−, SeO42−, NO3−, Cl− or Br− could partly replace the OH− anions in the channels. The incorporation of such anions into the M3(TeO3)2(OH)2 structure was confirmed by energy-dispersive X-ray spectrometry (EDS) measurements and Raman spectroscopy of selected single-crystals.

Item Details

Item Type:Refereed Article
Keywords:oxidotellurates(IV); first-row transition metals; hydrothermal synthesis; crystal chemistry; crystal structure determination; disorder
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Crystallography
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Missen, OP (Dr Owen Missen)
ID Code:154980
Year Published:2022
Web of Science® Times Cited:1
Deposited By:CODES ARC
Deposited On:2023-01-20
Last Modified:2023-01-25
Downloads:0

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