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The Order–Disorder (OD) Polytypism of [Cu2ZnTeO4]2+[SO4·H2O]2−
journal contribution
posted on 2023-05-21, 15:52 authored by Stoger, B, Weil, M, Owen MissenOwen Missen, Mills, SJ[Cu2ZnTeO4]2+[SO4·H2O]2− crystallizes as a category IV order‒disorder (OD) structure with two kinds of nonpolar layers with the formal composition [Cu2ZnTeO4]2+ and [SO4·H2O]2−, respectively. Reflection symmetry that is only valid for the [Cu2ZnTeO4]2+ layers leads to two ways of placing the [SO4·H2O]2− layers. Two of the polytypes are of a maximum degree of order (MDO1: P21/m and MDO2: Pnma). The crystal under investigation is mostly of the MDO2 polytype. Remaining positive electron density peaks in the difference Fourier maps indicate fragments of the MDO1 polytype.
History
Publication title
Crystal Research and TechnologyVolume
55Issue
5Article number
1900182Number
1900182Pagination
1-5ISSN
0232-1300Department/School
School of Natural SciencesPublisher
Wiley-V C H Verlag GmbhPlace of publication
Po Box 10 11 61, Weinheim, Germany, D-69451Rights statement
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, WeinheimRepository Status
- Restricted