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Structural revision of parvistemoamide: informing biosynthetic proposals of Stemona alkaloids

Citation

Olivier, WJ and Smith, JA and Bissember, AC, Structural revision of parvistemoamide: informing biosynthetic proposals of Stemona alkaloids, Organic Letters, 24, (31) pp. 5772-5776. ISSN 1523-7060 (2022) [Refereed Article]


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DOI: doi:10.1021/acs.orglett.2c02254

Abstract

The natural product parvistemoamide was isolated in 1991 and has ostensibly eluded synthesis. Its distinctive assigned structure represents the first and only Stemona alkaloid within its class. For over 30 years, this structure has influenced biosynthetic proposals concerning this family of natural products. Following synthetic studies and comprehensive analysis of relevant literature, a revised structure of parvistemoamide is proposed that is consistent with the fundamental Stemona alkaloid stemoamide.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Organic chemistry
Research Field:Organic chemical synthesis
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Olivier, WJ (Mr Wesley Olivier)
UTAS Author:Smith, JA (Associate Professor Jason Smith)
UTAS Author:Bissember, AC (Associate Professor Alex Bissember)
ID Code:152192
Year Published:2022
Funding Support:Australian Research Council (FT200100049)
Deposited By:Chemistry
Deposited On:2022-08-12
Last Modified:2022-09-02
Downloads:0

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