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Catalytic role of amines in activation of PhICl2 from a computational point of view

journal contribution
posted on 2023-05-21, 07:39 authored by Farshadfar, K, Alireza AriafardAlireza Ariafard

We thoroughly investigated mechanistic features of dichlorination of diazoacetates using PhICl2 catalysed by pyridine. We found that the pyridine serves as a catalyst for decomposition of PhICl2 to PhI and Cl2, leading to the dichlorination step being driven by the in situ generated Cl2. This type of activation was found to be applicable to other amine-catalysed chlorination reactions using PhICl2.

Funding

Australian Research Council

University of Wollongong

History

Publication title

Chemical Communications

Volume

57

Issue

72

Pagination

9108-9111

ISSN

1359-7345

Department/School

College Office - College of Sciences and Engineering

Publisher

Royal Soc Chemistry

Place of publication

Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0Wf

Rights statement

This journal is © The Royal Society of Chemistry 2021

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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    University Of Tasmania

    Categories

    Keywords

    DFT calculationshypervalent iodine chemistryredox chemistry

    Licence

    In Copyright

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