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Ion-pairs as a gateway to transmetalation: aryl transfer from boron to nickel and magnesium
Citation
Fabijanczuk, KC and Altalhi, WAO and Aldajani, AMO and Canty, AJ and McLuckey, SA and O'Hair, RAJ, Ion-pairs as a gateway to transmetalation: aryl transfer from boron to nickel and magnesium, Dalton Transactions, 51, (14) pp. 5699-5705. ISSN 1477-9226 (2022) [Refereed Article]
Copyright Statement
This journal is © The Royal Society of Chemistry 2022
Abstract
Gas-phase ion-ion reactions between tris-1,10-phenantholine metal dications, [(phen)3M]2+ (where M = Ni and Mg), and the tetraphenylborate anion yield the ion-pairs {[(phen)3M]2+[BPh4]−}+. The ion-pairs undergo transmetalation upon loss of a phen ligand to give the organometallic complexes [(phen)2M(Ph)]+. DFT calculations, used to determine the energy barriers for the transmetalation reactions and the hydrolysis reactions, are entirely consistent with the experimental results.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Transition metal chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the physical sciences |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| ID Code: | 149673 |
| Year Published: | 2022 |
| Deposited By: | Chemistry |
| Deposited On: | 2022-04-06 |
| Last Modified: | 2022-05-04 |
| Downloads: | 0 |
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