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Ore genesis and hydrothermal evolution of the Shaxi porphyry CuAu deposit, Anhui province, Eastern China: evidence from isotopes (SSrHO), pyrite, and fluid inclusions


Wang, S and Zhou, T and Hollings, P and Yuan, F and Fan, Y and White, NC and Zhang, L, Ore genesis and hydrothermal evolution of the Shaxi porphyry Cu-Au deposit, Anhui province, Eastern China: evidence from isotopes (S-Sr-H-O), pyrite, and fluid inclusions, Mineralium Deposita, 56 pp. 767-788. ISSN 0026-4598 (2021) [Refereed Article]

DOI: doi:10.1007/s00126-020-00995-5


The Shaxi porphyry CuAu deposit is located in the northern part of the Luzong Basin on the outer edge of the southern Middle-Lower Yangtze River metallogenic belt, China. It is typical of the porphyry CuAu deposits in the metallogenic belt, with more than 1 Mt Cu at 0.55 wt% and 45 tons Au at 0.47 g/t. Hydrothermal alteration consists of a core of potassic alteration overprinted by a phyllic alteration zone. Propylitic alteration occurs peripheral to the potassic zone, but can also be recognized in the core of the deposit, where vein density is low. The main mineralization occurs as sulfide veinlets in the potassic zone where it is superposed by phyllic alteration. The paragenetic sequence show that chalcopyrite began to precipitate late in stage 1, associated with potassic alteration, forming quartz-sulfide veins with potassium feldspar halos, and reached a peak in stage 3, forming chalcopyrite-pyrite quartz anhydrite chlorite illite veins that accompanied phyllic alteration. Sulfur, hydrogen-oxygen and strontium isotopes, fluid inclusions, and pyrite trace element data indicate that the stage 1 assemblage associated with potassic alteration were deposited from a magmatic brine. With the change from lithostatic to hydrostatic pressure late in stage 1, the brine generated stage 1 g quartz-pyrite-chalcopyrite anhydrite bornite molybdenite potassium feldspar veins with minor copper and gold. Mixing with minor external fluids (meteoric water or gypsum-saturated groundwater) in stage 2 triggered the peripheral propylitic alteration. As the proportion of external fluid increased with the onset of hydrostatic conditions, it changed the redox state and composition of the hydrothermal system, resulting in extensive stage 3 Cu and Au precipitation with phyllic alteration. Argillic alteration associated with stage 4 veins was generated by external fluids mixed with minor hydrothermal fluid, at shallow depths.

Item Details

Item Type:Refereed Article
Keywords:fluid inclusion, sulfur and strontium isotope, pyrite geochemistry, Shaxi deposit, Middle-Lower Yangtze Metallogenic Belt
Research Division:Earth Sciences
Research Group:Geochemistry
Research Field:Isotope geochemistry
Objective Division:Mineral Resources (Excl. Energy Resources)
Objective Group:Mineral exploration
Objective Field:Copper ore exploration
UTAS Author:White, NC (Professor Noel White)
UTAS Author:Zhang, L (Dr Lejun Zhang)
ID Code:149039
Year Published:2021
Web of Science® Times Cited:3
Deposited By:CODES ARC
Deposited On:2022-03-02
Last Modified:2022-04-08

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