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Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations

journal contribution
posted on 2023-05-21, 01:07 authored by Curtis HoCurtis Ho, Angus OldingAngus Olding, Rebecca FullerRebecca Fuller, Allan CantyAllan Canty, Lucas, NT, Alexander BissemberAlexander Bissember
This study investigates the mechanism of Suzuki-Miyaura Csp2-Csp2 cross-couplings facilitated by PCP-type nickel(II) pincer complexes. By employing a combination of standard experimental and theoretical methods, it is proposed that a nickel(I)/(III) cycle is involved in this reaction and single-electron pathways likely operate in this transformation.

Funding

Australian Research Council

History

Publication title

Organometallics

Volume

40

Issue

14

Pagination

2305-2310

ISSN

0276-7333

Department/School

School of Natural Sciences

Publisher

Amer Chemical Soc

Place of publication

1155 16Th St, Nw, Washington, USA, Dc, 20036

Rights statement

© 2021 American Chemical Society

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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    University Of Tasmania

    Categories

    Keywords

    Suzuki-Miyauracross-couplingnickelmechanism

    Licence

    In Copyright

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