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Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations
Citation
Ho, CC and Olding, A and Fuller, RO and Canty, AJ and Lucas, NT and Bissember, AC, Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations, Organometallics, 40, (14) pp. 2305-2310. ISSN 0276-7333 (2021) [Refereed Article]
Copyright Statement
© 2021 American Chemical Society
DOI: doi:10.1021/acs.organomet.1c00033
Abstract
This study investigates the mechanism of Suzuki-Miyaura Csp2-Csp2 cross-couplings facilitated by PCP-type nickel(II) pincer complexes. By employing a combination of standard experimental and theoretical methods, it is proposed that a nickel(I)/(III) cycle is involved in this reaction and single-electron pathways likely operate in this transformation.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | Suzuki-Miyaura, cross-coupling, nickel, mechanism |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | Organometallic chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Ho, CC (Dr Curtis Ho) |
| UTAS Author: | Olding, A (Mr Angus Olding) |
| UTAS Author: | Fuller, RO (Dr Rebecca Fuller) |
| UTAS Author: | Canty, AJ (Professor Allan Canty) |
| UTAS Author: | Bissember, AC (Associate Professor Alex Bissember) |
| ID Code: | 145553 |
| Year Published: | 2021 |
| Funding Support: | Australian Research Council (DP200101714) |
| Deposited By: | Chemistry |
| Deposited On: | 2021-07-26 |
| Last Modified: | 2021-09-02 |
| Downloads: | 0 |
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