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Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations

Citation

Ho, CC and Olding, A and Fuller, RO and Canty, AJ and Lucas, NT and Bissember, AC, Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations, Organometallics, 40, (14) pp. 2305-2310. ISSN 0276-7333 (2021) [Refereed Article]

Copyright Statement

2021 American Chemical Society

DOI: doi:10.1021/acs.organomet.1c00033

Abstract

This study investigates the mechanism of Suzuki-Miyaura Csp2-Csp2 cross-couplings facilitated by PCP-type nickel(II) pincer complexes. By employing a combination of standard experimental and theoretical methods, it is proposed that a nickel(I)/(III) cycle is involved in this reaction and single-electron pathways likely operate in this transformation.

Item Details

Item Type:Refereed Article
Keywords:Suzuki-Miyaura, cross-coupling, nickel, mechanism
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Organometallic chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Ho, CC (Dr Curtis Ho)
UTAS Author:Olding, A (Mr Angus Olding)
UTAS Author:Fuller, RO (Dr Rebecca Fuller)
UTAS Author:Canty, AJ (Professor Allan Canty)
UTAS Author:Bissember, AC (Associate Professor Alex Bissember)
ID Code:145553
Year Published:2021
Funding Support:Australian Research Council (DP200101714)
Deposited By:Chemistry
Deposited On:2021-07-26
Last Modified:2021-09-02
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