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Potentiometric detection of anions separated by liquid chromatography using a metallic silver wire electrode

Citation

Chen, ZL and Alexander, PW, Potentiometric detection of anions separated by liquid chromatography using a metallic silver wire electrode, Instrumentation Science and Technology, 26, (4) pp. 421-431. ISSN 1073-9149 (1998) [Refereed Article]

DOI: doi:10.1080/10739149808001909

Abstract

A silver metallic wire electrode, coated with AgCl, used for potentiometric detection of inorganic anions in liquid chromatography, is described. The electrode response to the anions was evaluated by both static and flow injection measurements, and results have shown that the electrode exhibits sensitive response to Cl- and SCN- with a detection limit of 10-6 M. The electrode was used as a potentiometric detector for the determination of anions following separation by ion chromatography using the eluent containing 5 mM phthalate at pH 4.2. Calibration plots were not linear, but give a useful working range of 5 ×10-5 to 3 × 10-2 M. It also demonstrated to be a useful detector for the detection of anions separated, where the separation of anions was preformed with a C18 column using a 0.1 mM octylammonium salicylate as an ion-paring reagent, by ion-pair chromatography. The determination of chloride in waste water samples were demonstrated by proposed method.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Analytical Chemistry
Research Field:Instrumental Methods (excl. Immunological and Bioassay Methods)
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Alexander, PW (Professor Peter Alexander)
ID Code:14339
Year Published:1998
Web of Science® Times Cited:6
Deposited By:Applied Science
Deposited On:1998-08-01
Last Modified:2011-08-09
Downloads:0

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