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Non-suppressed ion chromatography of cations on silica gel modified with aluminium
journal contribution
posted on 2023-05-16, 11:17 authored by Ohta, K, Morikawa, H, Tanaka, K, Paul HaddadPaul HaddadThe presence of aluminium in the silica matrix causes an enhancement of the acidity of the silanol group on silica gel. Therefore, in order to prepare silica-based cation-exchangers for ion chromatography (IC) under strongly acidic eluent conditions, modification of silica gel with aluminium using a coating method was carried out. As a result, aluminium-adsorbing silica gels were found to act as a cation-exchangers under strongly acidic eluent conditions and were successfully applied to the conductimetric detection IC for the separation of common mono- and divalent cations using nitric acid-2,6-pyridinedicarboxylic acid eluent. These results strongly indicate that the modification is a simple and effective way for the preparation of advanced silica-based cation-exchangers for IC.
History
Publication title
Journal of Chromatography AVolume
804Issue
1-2Pagination
171-177ISSN
0021-9673Department/School
School of Natural SciencesPublisher
ElsevierPlace of publication
The NetherlandsRepository Status
- Restricted