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Separation of metal ions using a polymeric reversed-phase column and a Methylthymol Blue containing mobile phase
journal contribution
posted on 2023-05-16, 11:16 authored by Brett PaullBrett Paull, Nesterenko, PN, Nurdin, M, Paul HaddadPaul HaddadA polystyrene–divinylbenzene reversed-phase column has been used in conjunction with a mobile phase containing methylthymol blue for the separation and visible detection of Mn2+, Zn2+, Cd2+ and Pb2+ in the presence of excess concentrations of matrix metals. Retention is due to the formation of a dynamically coated chelating stationary phase and is dependent upon mobile phase pH and ligand concentration. The method showed a different selectivity when compared to a pre-coated Methylthymol Blue chelating column and offers improved separation efficiency. Detection limits for Zn2+ and Pb2+ of 1 µM were achieved in solutions containing up to 1 M NaCl, following the post-column addition of a pH 5.9 buffer.
History
Publication title
Analytical CommunicationsVolume
35Pagination
17-20ISSN
1359-7337Department/School
School of Natural SciencesPublisher
Royal Society of ChemistryPlace of publication
United KingdomRights statement
Copyright © 1998 Royal Society of ChemistryRepository Status
- Restricted