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New insights on the reaction of alkyl 3-oxo-4-(triphenylphosphoranylidene)butanoate and aldehydes under concentrated condensation conditions. One-pot synthesis of highly functionalised 6-oxocyclohex-4-ene-1,3-dicarboxylates

journal contribution
posted on 2023-05-16, 11:15 authored by Moorhoff, CM, Schneider, DF, Winkler, D
A general method for the synthesis of substituted cyclohexenones 5 from the condensation of acetoacetate phosphonium ylide 1 and saturated and unsaturated aldehydes 2, without activation, is described.

History

Publication title

Journal of Chemical Research S

Issue

12

Pagination

3461-3483

ISSN

0308-2342

Department/School

School of Natural Sciences

Publisher

Royal Society of Chemistry

Place of publication

United Kingdom

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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