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A route to new methylpalladium(II) carbene complexes


Green, MJ and Cavell, KJ and Skelton, BW and White, AH, A route to new methylpalladium(II) carbene complexes, Journal of Organometallic Chemistry, 554, (2) pp. 175-179. ISSN 0022-328X (1998) [Refereed Article]

DOI: doi:10.1016/S0022-328X(97)00671-2


The nucleophilic carbene, 1,3-dimethylimidazolin-2-ylidene, reacts with PdClMe(cod) to produce the first methylpalladium(II) carbene complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(μ-Cl)]2 1, from which the preparation of other methylpalladium carbene complexes may proceed, and the crystal structure of one such complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(NC5H4CO 2-2)], is reported.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:Transition metal chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Green, MJ (Ms Melinda Jane Green)
UTAS Author:Cavell, KJ (Professor Kingsley Cavell)
ID Code:14126
Year Published:1998
Web of Science® Times Cited:40
Deposited By:Chemistry
Deposited On:1998-08-01
Last Modified:2011-08-09

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