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A route to new methylpalladium(II) carbene complexes

journal contribution
posted on 2023-05-16, 11:15 authored by Green, MJ, Cavell, KJ, Skelton, BW, White, AH
The nucleophilic carbene, 1,3-dimethylimidazolin-2-ylidene, reacts with PdClMe(cod) to produce the first methylpalladium(II) carbene complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(μ-Cl)]2 1, from which the preparation of other methylpalladium carbene complexes may proceed, and the crystal structure of one such complex, [PdMe(1,3-dimethylimidazolin-2-ylidene)(NC5H4CO 2-2)], is reported.

History

Publication title

Journal of Organometallic Chemistry

Volume

554

Pagination

175-179

ISSN

0022-328X

Department/School

School of Natural Sciences

Publisher

Elsevier

Place of publication

The Netherlands

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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    University Of Tasmania

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    In Copyright

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