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Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)(2)-C,P}{(pz)(3)BH-N,N '} and Pd(C6H4C5H4N-C-2,N '){(pz)(3)BH-N,N '}

Citation

Canty, AJ and Hoare, JL and Skelton, BW and White, AH and van Koten, G, Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)(2)-C,P}{(pz)(3)BH-N,N '} and Pd(C6H4C5H4N-C-2,N '){(pz)(3)BH-N,N '}, Journal of Organometallic Chemistry, 552, (1-2) pp. 23-29. ISSN 0022-328X (1998) [Refereed Article]

DOI: doi:10.1016/S0022-328X(97)00576-7

Abstract

The cyclopalladated complexes Pd{2-CH2C6H4P(o-tol)2}{(pz) nBH4-n} and Pd(C6H4C5H4N-C 2,N′){(pz)nBH4-n} [n=2, 3; pz=pyrazol-1-yl] have been synthesised from the corresponding halide bridged cyclometallated dimers; the crystal structures of the complexes for which n=3 have been determined. The complexes Pd{2-CH2C6H4P(o-tol)2}{(pz) nBH4-n} (n=2, 3) and [Pd{2-CH2C6H4P(o-tol)2}(μ-O 2CMe)]2 are unreactive towards oxidation by alkyl halides, iodobenzene and 4-bromoanisole.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Other Chemical Sciences
Research Field:Organometallic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Canty, AJ (Professor Allan Canty)
Author:Hoare, JL (Mr Jason Lancelot Hoare)
ID Code:14086
Year Published:1998
Web of Science® Times Cited:20
Deposited By:Chemistry
Deposited On:1998-08-01
Last Modified:2011-08-09
Downloads:0

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