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Peroxide bleaching using zeolites. Part 1: peroxide decomposition
journal contribution
posted on 2023-05-16, 11:14 authored by Finnegan, DJ, Karen Stack, Dunn, LAAddition of certain levels of zeolite and sodium citrate to hydrogen peroxide solutions containing manganese decreased the rate of peroxide decomposition. There were differences in the ability of commercially available zeolites to reduce decomposition of peroxide. Addition of small amounts of sodium citrate to a particular zeolite system improved its ability to chelate metal ions. Sodium citrate appears to act as a transfer agent, facilitating the migration of metal ions to the zeolite. However addition of excess zeolite and citrate increase manganese induced peroxide decomposition. If the manganese-oxygen complex that decomposes peroxide under alkaline conditions was allowed to form prior to the addition of either the zeolite or citrate then the two chelating agents were unable to interact with the complex and prevent decomposition.
History
Publication title
Appita JournalVolume
51Pagination
219-223ISSN
1038-6807Department/School
School of Natural SciencesPublisher
AppitaPlace of publication
Melbourne AustraliaRepository Status
- Restricted