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Chlorite and epidote mineral chemistry in porphyry ore systems: a case study of the Northparkes District, New South Wales, Australia

Citation

Pacey, A and Wilkinson, JJ and Cooke, DR, Chlorite and epidote mineral chemistry in porphyry ore systems: a case study of the Northparkes District, New South Wales, Australia, Economic Geology, 115, (4) pp. 701-727. ISSN 0361-0128 (2020) [Refereed Article]

Copyright Statement

Copyright 2020 Society of Economic Geologists, Inc.

DOI: doi:10.5382/econgeo.4700

Abstract

Propylitic alteration, characterized by the occurrence of chlorite and epidote, is typically the most extensive and peripheral alteration facies developed around porphyry ore deposits. However, exploration within this alteration domain is particularly challenging, commonly owing to weak or nonexistent whole-rock geochemical gradients and the fact that similar assemblages can be developed in other geologic settings, particularly during low-grade metamorphism. We document and interpret systematic spatial trends in the chemistry of chlorite and epidote from propylitic alteration around the E48 and E26 porphyry Cu-Au deposits of the Northparkes district, New South Wales, Australia. These trends vary as a function of both distance from hydrothermal centers and alteration paragenesis.

The spatial trends identified in porphyry-related chlorite and epidote at Northparkes include (1) a deposit-proximal increase in Ti, As, Sb, and V in epidote and Ti in chlorite, (2) a deposit-distal increase in Co and Li in chlorite and Ba in epidote, and (3) a pronounced halo around deposits in which Mn and Zn in chlorite, as well as Mn, Zn, Pb, and Mg in epidote, are elevated. Chlorite Al/Si ratios and epidote Al/Fe ratios may show behavior similar to that of Mn-Zn or may simply decrease outward, and V and Ni concentrations in chlorite are lowest in the peak Mn-Zn zone. In comparison to porphyry-related samples, chlorite from the regional metamorphic assemblage in the district contains far higher concentrations of Li, Ca, Ba, Pb, and Cu but much less Ti. Similarly, metamorphic epidote contains higher concentrations of Sr, Pb, As, and Sb but less Bi and Ti.

These chlorite and epidote compositional trends are the net result of fluid-mineral partitioning under variable physicochemical conditions within a porphyry magmatic-hydrothermal system. They are most easily explained by the contribution of spent magmatic-derived ore fluid(s) into the propylitic domain. It is envisaged that such fluids experience progressive cooling and reduction in 𝑓s2 during outward infiltration into surrounding country rocks, with their pH controlled by the extent of rock-buffering experienced along the fluid pathway.

Item Details

Item Type:Refereed Article
Research Division:Earth Sciences
Research Group:Geology
Research Field:Resource geoscience
Objective Division:Mineral Resources (Excl. Energy Resources)
Objective Group:Mineral exploration
Objective Field:Copper ore exploration
UTAS Author:Wilkinson, JJ (Professor Jamie Wilkinson)
UTAS Author:Cooke, DR (Professor David Cooke)
ID Code:139371
Year Published:2020
Funding Support:Australian Research Council (IH130200004)
Web of Science® Times Cited:14
Deposited By:CODES ARC
Deposited On:2020-06-12
Last Modified:2020-07-07
Downloads:0

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