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Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound

journal contribution
posted on 2023-05-20, 08:05 authored by Lee, JJ, Rebecca FullerRebecca Fuller, Sobolev, AN, Clausen, HF, Overgaard, J, Koutsantonis, GA, Iversen, BB, Spackman, MA
The title compound undergoes two order–disorder transitions between 15 and 299 K, dictated by ordering of the guest molecules in the host cages, and resulting in three related crystal structures. We anticipate behaviour of this kind to be widespread, and speculate that the concept of “the crystal structure” for individual Dianin's clathrates may be elusive.

History

Publication title

Chemical Communications

Volume

47

Issue

7

Pagination

2029-2031

ISSN

1359-7345

Department/School

School of Natural Sciences

Publisher

Royal Soc Chemistry

Place of publication

Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0Wf

Rights statement

Copyright 2011 The Royal Society of Chemistry

Repository Status

  • Restricted

Socio-economic Objectives

Expanding knowledge in the chemical sciences

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