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Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound

Citation

Lee, JJ and Fuller, RO and Sobolev, AN and Clausen, HF and Overgaard, J and Koutsantonis, GA and Iversen, BB and Spackman, MA, Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound, Chemical Communications, 47, (7) pp. 2029-2031. ISSN 1359-7345 (2011) [Refereed Article]

Copyright Statement

Copyright 2011 The Royal Society of Chemistry

DOI: doi:10.1039/C0CC04418K

Abstract

The title compound undergoes two order–disorder transitions between 15 and 299 K, dictated by ordering of the guest molecules in the host cages, and resulting in three related crystal structures. We anticipate behaviour of this kind to be widespread, and speculate that the concept of "the crystal structure" for individual Dianin's clathrates may be elusive.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Macromolecular and Materials Chemistry
Research Field:Nanochemistry and Supramolecular Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
UTAS Author:Fuller, RO (Dr Rebecca Fuller)
ID Code:135621
Year Published:2011
Web of Science® Times Cited:8
Deposited By:Chemistry
Deposited On:2019-11-05
Last Modified:2019-12-13
Downloads:0

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