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Temperature-dependent crystal structure of the isopropanol clathrate of Dianin's compound
journal contribution
posted on 2023-05-20, 08:05 authored by Lee, JJ, Rebecca FullerRebecca Fuller, Sobolev, AN, Clausen, HF, Overgaard, J, Koutsantonis, GA, Iversen, BB, Spackman, MAThe title compound undergoes two order–disorder transitions between 15 and 299 K, dictated by ordering of the guest molecules in the host cages, and resulting in three related crystal structures. We anticipate behaviour of this kind to be widespread, and speculate that the concept of “the crystal structure” for individual Dianin's clathrates may be elusive.
History
Publication title
Chemical CommunicationsVolume
47Issue
7Pagination
2029-2031ISSN
1359-7345Department/School
School of Natural SciencesPublisher
Royal Soc ChemistryPlace of publication
Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0WfRights statement
Copyright 2011 The Royal Society of ChemistryRepository Status
- Restricted