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Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene
Citation
Fuller, RO and Livesey, KL and Woodward, RC and McKinley, AJ and Skelton, BW and Koutsantonis, GA, Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene, Australian Journal of Chemistry, 67, (11) pp. 1588-1594. ISSN 0004-9425 (2014) [Refereed Article]
Copyright Statement
Copyright CSIRO 2014
DOI: doi:10.1071/CH14136
Abstract
Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn–Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic chemistry |
| Research Field: | F-block chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding knowledge |
| Objective Field: | Expanding knowledge in the chemical sciences |
| UTAS Author: | Fuller, RO (Dr Rebecca Fuller) |
| ID Code: | 135614 |
| Year Published: | 2014 |
| Web of Science® Times Cited: | 4 |
| Deposited By: | Chemistry |
| Deposited On: | 2019-11-05 |
| Last Modified: | 2019-12-13 |
| Downloads: | 0 |
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