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Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene


Fuller, RO and Livesey, KL and Woodward, RC and McKinley, AJ and Skelton, BW and Koutsantonis, GA, Magnetic studies of metal ion coordination clusters encapsulated with thiacalixarene, Australian Journal of Chemistry, 67, (11) pp. 1588-1594. ISSN 0004-9425 (2014) [Refereed Article]

Copyright Statement

Copyright CSIRO 2014

DOI: doi:10.1071/CH14136


Three thiacalix[4]arene polynuclear complexes have been prepared by literature methods for detailed magnetic investigation. The [Fe3O(L)2] (LH4 = thiacalix[4]arene) complex is found to exhibit interesting anti-ferromagnetic exchange coupling. Jahn–Teller distortion in [Cu4(L)2] complex leads to strong anti-ferromagnetic coupling at low temperatures. The temperature-dependent susceptibility of the [(μ-H2O)Eu2(LH)2(DMF)4] complex is well described by a ground state involving the thermal population of the lowest three excited states.

Item Details

Item Type:Refereed Article
Research Division:Chemical Sciences
Research Group:Inorganic chemistry
Research Field:F-block chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Fuller, RO (Dr Rebecca Fuller)
ID Code:135614
Year Published:2014
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2019-11-05
Last Modified:2019-12-13

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