eCite Digital Repository

Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies

Citation

Reid, BL and Woodward, RC and Fuller, RO and Sobolev, AN and Skelton, BW and Ogden, MI and Massi, M, Investigation of the structure and magnetism in lanthanide ß-triketonate tetranuclear assemblies, Journal of Coordination Chemistry, 69, (11-13) pp. 1852-1863. ISSN 0095-8972 (2016) [Refereed Article]

Copyright Statement

© 2016 Informa UK Limited, trading as Taylor & Francis Group

DOI: doi:10.1080/00958972.2016.1180375

Abstract

The preparation of discrete tetranuclear lanthanide/alkali metal (Ae) assemblies bearing a tribenzoylmethane ligand (LH) is discussed. These assemblies have the general formula [Ln(Ae·HOEt)(L)4]2, where Ln3+ = Gd3+, Tb3+, Dy3+, Ho3+ and Ae+ = Na+, K+, Rb+. The coordination geometries of the lanthanide species were analyzed and compared, revealing a trend between an eight-coordinate square antiprism and triangular dodecahedron dependent on the nature of lanthanide, alkali metal, and lattice solvent. The potassium-containing analogs were also analyzed for their magnetic susceptibility.

Item Details

Item Type:Refereed Article
Keywords:lanthanides, magnetism, triketonates, diketonates, assemblies
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:f-Block Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
UTAS Author:Fuller, RO (Dr Rebecca Fuller)
ID Code:135604
Year Published:2016
Web of Science® Times Cited:1
Deposited By:Chemistry
Deposited On:2019-11-05
Last Modified:2019-12-05
Downloads:0

Repository Staff Only: item control page