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Magnesite formation in playa environments near Atlin, British Columbia, Canada

Citation

Power, IM and Harrison, AL and Dipple, GM and Wilson, SA and Barker, SLL and Fallon, SJ, Magnesite formation in playa environments near Atlin, British Columbia, Canada, Geochimica et Cosmochimica Acta, 255 pp. 1-24. ISSN 0016-7037 (2019) [Refereed Article]

Copyright Statement

Copyright 2019 Elsevier Ltd.

DOI: doi:10.1016/j.gca.2019.04.008

Abstract

The hydromagnesite-magnesite playas near Atlin, British Columba, Canada are unique Mg-carbonate depositional environments that have formed at Earth’s surface since the end of the last deglaciation. This study elucidates the mechanisms, pathways, and rates of magnesite (MgCO3) formation in these near-surface environments, which are challenging to study in short-duration laboratory experiments because magnesite precipitation is extremely slow at low temperature. The Atlin playas, having formed over millennia, contain abundant magnesite as well as a suite of other Mg- and Ca-carbonate minerals. Mineralogical and textural evidence demonstrate that hydromagnesite [Mg5(CO3)4(OH)2·4H2O] forms at least in part through transformation of more hydrated phases, e.g., lansfordite (MgCO3·5H2O). Deposition of these hydrated Mg-carbonate minerals is limited by the evaporative flux, and thus, is effectively transport-controlled at the scale of the playas. Magnesite is a spatially distinct phase from hydromagnesite and its crystal morphology varies with depth indicating variable crystal growth mechanisms and precipitation rates. Particle size distributions and mineral abundance data indicate that magnesite formation is nucleation-limited. Furthermore, mineralogical data as well as stable and radiogenic isotope data support magnesite formation starting after the majority of hydromagnesite had been deposited likely resulting from long induction times and slow precipitation rates. Hydrated Mg-carbonate minerals precipitate relatively rapidly and control pore water chemistry while magnesite remains highly supersaturated, and thus, is reaction-controlled. This difference in controlling regime allows for magnesite abundance to increase over time without the loss of hydromagnesite such as through its transformation, which the data also does not support. We estimate rates of magnesite formation (nucleation + crystal growth) in the range of 10-17 to 10-16 mol/cm2/s over approximately 8000 years. This study helps to elucidate the geochemical conditions needed to form Mg-carbonate minerals in ancient and modern sedimentary environments and provides insights into facilitating long-term storage of anthropogenic CO2 within Mg-carbonate minerals.

Item Details

Item Type:Refereed Article
Keywords:magnesite, hydromagnesite, playas, mineral formation rates, CO2 sequestration
Research Division:Environmental Sciences
Research Group:Soil Sciences
Research Field:Carbon Sequestration Science
Objective Division:Mineral Resources (excl. Energy Resources)
Objective Group:Environmentally Sustainable Mineral Resource Activities
Objective Field:Management of Greenhouse Gas Emissions from Mineral Resource Activities
UTAS Author:Barker, SLL (Dr Shaun Barker)
ID Code:133647
Year Published:2019
Web of Science® Times Cited:1
Deposited By:CODES ARC
Deposited On:2019-07-05
Last Modified:2019-08-21
Downloads:0

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