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Absence of common five-co-ordinate intermediates in the induced reactions of some cobalt(III)–acido complexes

Citation

Buckingham, DA and Edwards, JD and Lewis, TW and McLaughlin, GM, Absence of common five-co-ordinate intermediates in the induced reactions of some cobalt(III)-acido complexes, Chemical Communications, 20 pp. 892-894. ISSN 1359-7345 (1978) [Refereed Article]

DOI: doi:10.1039/C39780000892

Abstract

The stereochemistry of the aqua and hydroxo products fromed in the induced aquation (Hg2+, Ag+, NO+) and base hydrolysis reactions of anti-p, syn-p, and s-[Co(Metren)NH3X]n+ ions (n= 2 or 3; tren = 2,2′,2″-triaminotriethylamine; X = Cl, Br, N3, NH3; p = primary, s = secondary) show a dependence on leaving group, type of reaction, and reactant stereochemistry, thereby eliminating the formation of common intermediates.

Item Details

Item Type:Refereed Article
Keywords:stereochemistry, base electrolysis
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Bioinorganic Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
UTAS Author:Lewis, TW (Dr Trevor Lewis)
ID Code:130693
Year Published:1978
Web of Science® Times Cited:20
Deposited By:Chemistry
Deposited On:2019-02-07
Last Modified:2019-02-20
Downloads:0

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