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Absence of common five-co-ordinate intermediates in the induced reactions of some cobalt(III)–acido complexes
journal contribution
posted on 2023-05-20, 00:37 authored by Buckingham, DA, Edwards, JD, Trevor LewisTrevor Lewis, McLaughlin, GMThe stereochemistry of the aqua and hydroxo products fromed in the induced aquation (Hg2+, Ag+, NO+) and base hydrolysis reactions of anti-p, syn-p, and s-[Co(Metren)NH3X]n+ ions (n= 2 or 3; tren = 2,2′,2″-triaminotriethylamine; X = Cl, Br, N3, NH3; p = primary, s = secondary) show a dependence on leaving group, type of reaction, and reactant stereochemistry, thereby eliminating the formation of common intermediates.
History
Publication title
Chemical CommunicationsVolume
20Pagination
892-894ISSN
1359-7345Department/School
School of Natural SciencesPublisher
Royal Soc ChemistryPlace of publication
Thomas Graham House, Science Park, Milton Rd, Cambridge, England, Cambs, Cb4 0WfRepository Status
- Restricted