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Electrochemically driven actuators from conducting polymers, hydrogels, and carbon nanotubes


Spinks, GM and Wallace, GG and Lewis, TW and Fifield, LS and Dai, L and Baughman, RH, Electrochemically driven actuators from conducting polymers, hydrogels, and carbon nanotubes, Proceedings SPIE, 13-15 December 2000, Melbourne, pp. 223-231. (2001) [Refereed Conference Paper]

DOI: doi:10.1117/12.424410


The mechanisms of actuation operating in polymeric actuators are reviewed along with a comparison of actuator performance. Polymer hydrogel actuators show very large dimensional changes, but relatively low response times. The mechanism of actuation involves several processes including electro-osmosis and electrochemical effects. Conducting polymer actuators operate by Faradaic reactions causing oxidation and reduction of the polymer backbone. Associated ion movements produce dimensional changes of typically up to 3%. The maximum stress achieved to date from conducting polymers is not more than 10 MPA. Carbon nanotubes have recently been demonstrated as new actuator materials. The nanotubes undergo useful dimensional changes (approximately 1%) but have the capacity to respond very rapidly (kHz) and generate giant stresses (600 MPa). The advantages of nanotube actuators stem from their exceptional mechanical properties and the non-Faradaic actuation mechanism.

Item Details

Item Type:Refereed Conference Paper
Keywords:polymers, hydrogels, carbon nanotubes
Research Division:Chemical Sciences
Research Group:Macromolecular and materials chemistry
Research Field:Inorganic materials (incl. nanomaterials)
Objective Division:Expanding Knowledge
Objective Group:Expanding knowledge
Objective Field:Expanding knowledge in the chemical sciences
UTAS Author:Lewis, TW (Associate Professor Trevor Lewis)
ID Code:130657
Year Published:2001
Web of Science® Times Cited:4
Deposited By:Chemistry
Deposited On:2019-02-07
Last Modified:2019-02-20

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