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Non-classical anionic naked N-heterocyclic carbenes: fundamental properties and emerging applications in synthesis and catalysis
Citation
Leow, MY and Ho, CC and Gardiner, MG and Bissember, AC, Non-classical anionic naked N-heterocyclic carbenes: fundamental properties and emerging applications in synthesis and catalysis, Catalysts, 8, (12) Article 620. ISSN 2073-4344 (2018) [Refereed Article]
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Copyright Statement
Copyright 2018 The Authors. Licensed under Creative Commons Attribution 4.0 International (CC BY 4.0) https://creativecommons.org/licenses/by/4.0/
Abstract
Ongoing research exploring the chemistry of N-heterocyclic carbenes (NHCs) has led to the development and discovery of new NHC subclasses that deviate beyond Arduengo’s prototypical N,N′-disubstituted imidazol-2-ylidene-based structures. These systems continue to enable and extend the fundamental role of NHC ligands in synthesis and catalysis. In this regard, the advent of protic NHCs has garnered particular interest. This derives in part from their applications to the selective preparation of unique molecular scaffolds and their unprecedented bifunctional reactivity, which can be exploited in transition metal-catalyzed processes. In comparison, the synthetic applications of closely related anionic naked NHCs remain rather underexplored. With this in mind, this review highlights the interesting fundamental properties of non-classical anionic naked NHCs, and focuses on their emerging applications in synthesis and catalysis.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | N-heterocyclic carbenes, non-classical NHCs, protic NHCs, naked NHCs, catalysis |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Inorganic Green Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Leow, MY (Ms Mei Leow) |
| UTAS Author: | Ho, CC (Dr Curtis Ho) |
| UTAS Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
| UTAS Author: | Bissember, AC (Dr Alex Bissember) |
| ID Code: | 129599 |
| Year Published: | 2018 |
| Deposited By: | Chemistry |
| Deposited On: | 2018-12-10 |
| Last Modified: | 2019-03-06 |
| Downloads: | 0 |
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