eCite Digital Repository

Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity

Citation

Adly, FG and Bollard, H and Gardiner, MG and Ghanem, A, Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity, Catalysts, 8, (7) Article 268. ISSN 2073-4344 (2018) [Refereed Article]


Preview
PDF
1Mb
  

Copyright Statement

2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

DOI: doi:10.3390/catal8070268

Abstract

The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.

Item Details

Item Type:Refereed Article
Keywords:catalysis, synthesis, structure, dirhodium(II) complexes, Rh2(S-PTTL)4, asymmetric catalysis, cyclopropanation, X-ray crystallography, chiral catalysis, metal-carbene, phenyliodonium ylide
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Gardiner, MG (Associate Professor Michael Gardiner)
ID Code:128706
Year Published:2018
Deposited By:Chemistry
Deposited On:2018-10-08
Last Modified:2018-11-08
Downloads:6 View Download Statistics

Repository Staff Only: item control page