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Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity
Citation
Adly, FG and Bollard, H and Gardiner, MG and Ghanem, A, Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity, Catalysts, 8, (7) Article 268. ISSN 2073-4344 (2018) [Refereed Article]
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Copyright Statement
2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
Abstract
The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | catalysis, synthesis, structure, dirhodium(II) complexes, Rh2(S-PTTL)4, asymmetric catalysis, cyclopropanation, X-ray crystallography, chiral catalysis, metal-carbene, phenyliodonium ylide |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| UTAS Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
| ID Code: | 128706 |
| Year Published: | 2018 |
| Deposited By: | Chemistry |
| Deposited On: | 2018-10-08 |
| Last Modified: | 2019-03-06 |
| Downloads: | 50 View Download Statistics |
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