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128706 - Chiral Dirhodium II Carboxylates.pdf (1.46 MB)

Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity

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journal contribution
posted on 2023-05-19, 21:49 authored by Adly, FG, Bollard, H, Michael GardinerMichael Gardiner, Ghanem, A
The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.

History

Publication title

Catalysts

Volume

8

Issue

7

Article number

268

Number

268

Pagination

1-15

ISSN

2073-4344

Department/School

School of Natural Sciences

Publisher

MDPIAG

Place of publication

Switzerland

Rights statement

2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

Repository Status

  • Open

Socio-economic Objectives

Organic industrial chemicals (excl. resins, rubber and plastics); Expanding knowledge in the chemical sciences

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    University Of Tasmania

    Categories

    Keywords

    catalysissynthesisstructuredirhodium(II) complexesRh2(S-PTTL)4asymmetric catalysiscyclopropanationX-ray crystallographychiral catalysismetal-carbenephenyliodonium ylide

    Licence

    In Copyright

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