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Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity
Citation
Adly, FG and Bollard, H and Gardiner, MG and Ghanem, A, Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity, Catalysts, 8, (7) Article 268. ISSN 2073-4344 (2018) [Refereed Article]
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Abstract
The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | catalysis, synthesis, structure, dirhodium(II) complexes, Rh2(S-PTTL)4, asymmetric catalysis, cyclopropanation, X-ray crystallography, chiral catalysis, metal-carbene, phenyliodonium ylide |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Expanding Knowledge |
| Objective Group: | Expanding Knowledge |
| Objective Field: | Expanding Knowledge in the Chemical Sciences |
| Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
| ID Code: | 128706 |
| Year Published: | 2018 |
| Deposited By: | Chemistry |
| Deposited On: | 2018-10-08 |
| Last Modified: | 2018-10-10 |
| Downloads: | 0 |
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