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Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity

Citation

Adly, FG and Bollard, H and Gardiner, MG and Ghanem, A, Chiral dirhodium(II) carboxylates: New insights into the effect of ligand stereo-purity on catalyst structure and enantioselectivity, Catalysts, 8, (7) Article 268. ISSN 2073-4344 (2018) [Refereed Article]


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DOI: doi:10.3390/catal8070268

Abstract

The current report contributes to the understanding of the stereoselectivity of chiral dirhodium(II) carboxylate catalysts carrying N-protected tert-leucine ligands. Investigating the possible effect of ligand stereo-purity on catalyst structure and enantioselectivity was carried out. This was justified through a new X-ray crystal structure for Rh2(S,S,S,R-PTTL)4 diastereomer.

Item Details

Item Type:Refereed Article
Keywords:catalysis, synthesis, structure, dirhodium(II) complexes, Rh2(S-PTTL)4, asymmetric catalysis, cyclopropanation, X-ray crystallography, chiral catalysis, metal-carbene, phenyliodonium ylide
Research Division:Chemical Sciences
Research Group:Inorganic Chemistry
Research Field:Transition Metal Chemistry
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
Author:Gardiner, MG (Associate Professor Michael Gardiner)
ID Code:128706
Year Published:2018
Deposited By:Chemistry
Deposited On:2018-10-08
Last Modified:2018-10-10
Downloads:0

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