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Growth of a highly porous coordination polymer on a macroporous polymer monolith support for enhanced immobilized metal ion affinity chromatographic enrichment of phosphopeptides

Citation

Saeed, A and Maya, F and Xiao, DJ and Najam-ul-Haq, M and Svec, F and Britt, DK, Growth of a highly porous coordination polymer on a macroporous polymer monolith support for enhanced immobilized metal ion affinity chromatographic enrichment of phosphopeptides, Advanced Functional Materials, 24, (37) pp. 5790-5797. ISSN 1616-301X (2014) [Refereed Article]

Copyright Statement

Copyright 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

DOI: doi:10.1002/adfm.201400116

Abstract

A simple room temperature solution‐based method for the preparation of highly porous iron(III) benzenetricarboxylate coordination polymer films on the internal surface of a macroporous polystyrene‐divinylbenzene‐methacrylic acid polymer is reported. The resulting metal‐organic polymer hybrid (MOPH) maintains a high specific micropore surface area of 389 m2 g‐1 and thermal stability above 250 C in air. The MOPH preparation is readily adapted to a capillary column, yielding a flow‐through separation device with excellent flow permeability and modest back‐pressure. The excellent separation capability of the MOPH column is demonstrated by enriching phosphopeptides from mixtures of digested proteins. This approach to MOPH synthesis is easily implemented and likely adaptable to a wide range of coordination polymers and metal‐organic frameworks.

Item Details

Item Type:Refereed Article
Keywords:metal-organic frameworks, polymer monoliths, porous materials, porous coordination polymers
Research Division:Chemical Sciences
Research Group:Analytical Chemistry
Research Field:Separation Science
Objective Division:Expanding Knowledge
Objective Group:Expanding Knowledge
Objective Field:Expanding Knowledge in the Chemical Sciences
UTAS Author:Maya, F (Mr Fernando Maya Alejandro)
ID Code:127854
Year Published:2014
Web of Science® Times Cited:47
Deposited By:Chemistry
Deposited On:2018-08-19
Last Modified:2018-09-05
Downloads:0

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