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Nanoporous polymers from cross-linked polymer precursors via tert-butyl group deprotection and their carbon dioxide capture properties
Citation
Huang, J and Zhou, X and Lamprou, A and Maya, F and Svec, F and Turner, SR, Nanoporous polymers from cross-linked polymer precursors via tert-butyl group deprotection and their carbon dioxide capture properties, Chemistry of Materials, 27, (21) pp. 7388-7394. ISSN 0897-4756 (2015) [Refereed Article]
Copyright Statement
Copyright 2015 American Chemical Society
DOI: doi:10.1021/acs.chemmater.5b03114
Abstract
A two-step synthetic strategy has been developed to achieve functionalized nanoporous polymers via the deprotection of the cross-linked polymer precursors containing tert-butyl carboxylate-functionalized stilbene or styrene and N-phenylmaleimide alternating sequences. Three different deprotection methods to generate nanoporosity were examined in this work. The resulting nanoporous polymers showed a significant increase in BET surface area. The effects of cross-linking density and the stiffness of the alternating sequences on the nanoporosity of these polymers were studied. The resulting nanoporous polymers were also investigated as potential CO2 sorbents.
Item Details
Item Type: | Refereed Article |
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Keywords: | polymers, hypercrosslinking |
Research Division: | Chemical Sciences |
Research Group: | Inorganic chemistry |
Research Field: | Metal organic frameworks |
Objective Division: | Expanding Knowledge |
Objective Group: | Expanding knowledge |
Objective Field: | Expanding knowledge in the chemical sciences |
UTAS Author: | Maya, F (Mr Fernando Maya Alejandro) |
ID Code: | 127850 |
Year Published: | 2015 |
Web of Science® Times Cited: | 33 |
Deposited By: | Chemistry |
Deposited On: | 2018-08-19 |
Last Modified: | 2018-09-07 |
Downloads: | 0 |
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