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α-Cyanocarbanion complexes and their application in synthesis
Citation
Bissember, AC and Gardiner, MG and Wierenga, TS, α-Cyanocarbanion complexes and their application in synthesis, Journal of Organometallic Chemistry, 869 pp. 213-226. ISSN 0022-328X (2018) [Refereed Article]
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DOI: doi:10.1016/j.jorganchem.2018.04.010
Abstract
α-Cyanocarbanion complexes feature nitrile ligands containing deprotonated α-carbon atoms. This short review will focus on the various synthetic methods employed to prepare these complexes, the different binding modes they exhibit and their applications to the synthesis of alkylnitriles including β-hydroxyand β-aminonitriles, the formation of unique coupling products and as key intermediates in the reaction of acrylonitrile with various substrates in hydrophosphination and copolymerisation reactions.
Item Details
| Item Type: | Refereed Article |
|---|---|
| Keywords: | Cyanocarbanion, C‒H activation, nitrile, ketenimine, catalysis |
| Research Division: | Chemical Sciences |
| Research Group: | Inorganic Chemistry |
| Research Field: | Transition Metal Chemistry |
| Objective Division: | Manufacturing |
| Objective Group: | Industrial Chemicals and Related Products |
| Objective Field: | Organic Industrial Chemicals (excl. Resins, Rubber and Plastics) |
| Author: | Bissember, AC (Dr Alex Bissember) |
| Author: | Gardiner, MG (Associate Professor Michael Gardiner) |
| Author: | Wierenga, TS (Miss Tanita Wierenga) |
| ID Code: | 127061 |
| Year Published: | 2018 |
| Funding Support: | Australian Research Council (DP120101540) |
| Deposited By: | Chemistry |
| Deposited On: | 2018-07-09 |
| Last Modified: | 2018-07-09 |
| Downloads: | 0 |
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