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α-Cyanocarbanion complexes and their application in synthesis
journal contribution
posted on 2023-05-19, 19:24 authored by Alexander BissemberAlexander Bissember, Michael GardinerMichael Gardiner, Wierenga, TSα-Cyanocarbanion complexes feature nitrile ligands containing deprotonated α-carbon atoms. This short review will focus on the various synthetic methods employed to prepare these complexes, the different binding modes they exhibit and their applications to the synthesis of alkylnitriles including β-hydroxyand β-aminonitriles, the formation of unique coupling products and as key intermediates in the reaction of acrylonitrile with various substrates in hydrophosphination and copolymerisation reactions.
Funding
Australian Research Council
History
Publication title
Journal of Organometallic ChemistryVolume
869Pagination
213-226ISSN
0022-328XDepartment/School
School of Natural SciencesPublisher
Elsevier Science SaPlace of publication
Po Box 564, Lausanne, Switzerland, 1001Rights statement
© 2018 Elsevier B.V. All rights reserved.Repository Status
- Restricted