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α-Cyanocarbanion complexes and their application in synthesis

journal contribution
posted on 2023-05-19, 19:24 authored by Alexander BissemberAlexander Bissember, Michael GardinerMichael Gardiner, Wierenga, TS
α-Cyanocarbanion complexes feature nitrile ligands containing deprotonated α-carbon atoms. This short review will focus on the various synthetic methods employed to prepare these complexes, the different binding modes they exhibit and their applications to the synthesis of alkylnitriles including β-hydroxyand β-aminonitriles, the formation of unique coupling products and as key intermediates in the reaction of acrylonitrile with various substrates in hydrophosphination and copolymerisation reactions.

Funding

Australian Research Council

History

Publication title

Journal of Organometallic Chemistry

Volume

869

Pagination

213-226

ISSN

0022-328X

Department/School

School of Natural Sciences

Publisher

Elsevier Science Sa

Place of publication

Po Box 564, Lausanne, Switzerland, 1001

Rights statement

© 2018 Elsevier B.V. All rights reserved.

Repository Status

  • Restricted

Socio-economic Objectives

Organic industrial chemicals (excl. resins, rubber and plastics); Expanding knowledge in the chemical sciences

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